本地用户和组页面看起来像这样

要注意顺序列是很重要的，在管理员组的更新必须比用户创建命令一个更高的订单号。

一，你有你的组策略设置策略适用于在实验室（无论是通过OU目标或安全筛选，或WMI过滤）的设备。在下次重新启动本地itadmin用户将在每台机器上创建。

另外一个有趣的注意，当你选择谁添加到本地管理员组，当用户选择，您可以点击 ... 键，选择一个用户的的的域的这将允许其他人使用自己的域登录是在一个小套计算机的本地管理员不给他们做个管理员无处不在的权利。不过，他们需要能够登录使用这个工作的领域，所以如果你排除网络连接问题你目前的做法可能是一个更好的事情。

I am writing a C# program to be pushed out the labs I work in. The program is to create a local admin account(itadmin), set the password, set the password to never expire, and add the account to the local Administrators group. The program creates the new user account and sets everything correctly but when it attempts to add it to the admin group I get a very nondescript exception. Do I have the add to group correct in the first place? What am I missing?

using System;
using System.Collections.Generic;
using System.Linq;
using System.Text;
using System.DirectoryServices;

namespace CreateITAdmin
{
    class Program
    {
        static void Main(string[] args)
        {
            try
            {
                string userName = "itadmin";
                string userPassword = "password";

                Console.WriteLine("Building System Information");
                DirectoryEntry localMachine = new DirectoryEntry("WinNT://.,computer");
                DirectoryEntry newUser = localMachine.Children.Add(userName, "user");
                DirectoryEntry admGroup = new DirectoryEntry("WinNT://./Administrators,group");

                Console.WriteLine("Building User Information");
                newUser.Properties["FullName"].Value = "IT Administrative User";
                newUser.Invoke("Put", new object[] { "UserFlags", 0x10000 });

                Console.WriteLine("Setting User Password");
                newUser.Invoke("SetPassword", new object[] { userPassword });

                newUser.CommitChanges();

                Console.WriteLine("Adding itadmin to Administrators Group");
                admGroup.Invoke("Add", "WinNT://./" + newUser);

                Console.WriteLine("Cleaning Up");
                localMachine.Close();
                newUser.Close();
                admGroup.Close();
            }
            catch (System.DirectoryServices.DirectoryServicesCOMException E)
            {
                Console.WriteLine(E.Message.ToString());
                Console.ReadLine();
            }
            catch (System.Runtime.InteropServices.COMException E)
            {
                Console.WriteLine(E.Message.ToString());
                Console.ReadLine();
            }
            catch (System.Reflection.TargetInvocationException E)
            {
                Console.WriteLine(E.Message.ToString());
                Console.ReadLine();
            }
            catch (Exception E)
            {
                Console.WriteLine(E.Message.ToString());
                Console.ReadLine();
            }

            Console.WriteLine();
            Console.WriteLine("Press Any Key to Continue");
            Console.ReadLine();
            return;
        }
    }
}

The code output is below:

Building System Information
Building User Information
Setting User Password
Adding itadmin to Administrators Group
Exception has been thrown by the target of an invocation.

Any insight would be greatly appriciated.

UPDATE 1: With the help of @Grumbler85 the exceptionis listed below:

System.Reflection.TargetInvocationException: Exception has been thrown by the target 
of an invocation. ---> System.Runtime.InteropServices.COMException: A member could not
be added to or removed from the local group because the member does not exist. --- End
of inner exception stacktrace --- at System.DirectoryServices.DirectoryEntry.Invoke
(String methodName,Object[]args) at CreateITAdmin.Program.Main(String[]args)in 
H:\code\CS\CreateITAdmin\CreateITAdmin\Program.cs:line 37

Also with the help of @Grumbler85 I have been working on updating the library use to System.DirectoryServices.AccountManagement. It seems to be a lot easier and a lot more straight forward in use. More updates/details to come as I progress.

Update 2: I know this is a quick follow up but I was able to complete the update to the new namespace. After a minor hiccup with defining the machine, I was able to successfully create a user, set the password, update the password to never expire, and add the user to the administrators group. Thanks to @Grumbler85 for the update to the new namespace. The new code is below:

using System;
using System.Collections.Generic;
using System.Linq;
using System.Text;
using System.DirectoryServices;
using System.DirectoryServices.AccountManagement;

namespace CreateITAdmin
{
    class Program
    {
        static void Main(string[] args)
        {
            string userName = "itadmin";
            string userPassword = "IT-Engineering1";
            PrincipalContext systemContext = null;

            try
            {
                Console.WriteLine("Building System Information");
                systemContext = new PrincipalContext(ContextType.Machine, null);
            }
            catch (Exception E)
            {
                Console.WriteLine("Failed to create System Context.");
                Console.WriteLine("Exception: " + E);

                Console.WriteLine();
                Console.WriteLine("Press Any Key to Continue");
                Console.ReadLine();
                return;
            }

            //Check if user object already exists
            Console.WriteLine("Checking if User Exists.");
            UserPrincipal usr = UserPrincipal.FindByIdentity(systemContext, userName);
            if (usr != null)
            {
                Console.WriteLine(userName + " already exists. Exiting!!");
                Console.ReadLine();
                return;
            }

            //Create the new UserPrincipal object
            Console.WriteLine("Building User Information");
            UserPrincipal userPrincipal = new UserPrincipal(systemContext);
            userPrincipal.Name = userName;
            userPrincipal.DisplayName = "IT Administrative User";
            userPrincipal.PasswordNeverExpires = true;
            userPrincipal.SetPassword(userPassword);
            userPrincipal.Enabled = true;

            try
            {
                Console.WriteLine("Creating New User");
                userPrincipal.Save();
            }
            catch (Exception E)
            {
                Console.WriteLine("Failed to create user.");
                Console.WriteLine("Exception: " + E);

                Console.WriteLine();
                Console.WriteLine("Press Any Key to Continue");
                Console.ReadLine();
                return;
            }

            GroupPrincipal groupPrincipal = null;
            try
            {
                groupPrincipal = GroupPrincipal.FindByIdentity(systemContext, "Administrators");

                if (groupPrincipal != null)
                {
                    //check if user is a member
                    Console.WriteLine("Checking if itadmin is part of Administrators Group");
                    if (groupPrincipal.Members.Contains(systemContext, IdentityType.SamAccountName, userName))
                    {
                        Console.WriteLine("Administrators already contains " + userName);
                        return;
                    }
                    //Adding the user to the group
                    Console.WriteLine("Adding itadmin to Administrators Group");
                    groupPrincipal.Members.Add(userPrincipal);
                    groupPrincipal.Save();
                    return;
                }
                else
                {
                    Console.WriteLine("Could not find the group Administrators");
                }
            }
            catch (Exception E)
            {
                Console.WriteLine("Exception adding user to group.");
                Console.WriteLine("Exception: " + E);

                Console.WriteLine();
                Console.WriteLine("Press Any Key to Continue");
                Console.ReadLine();
            }

            Console.WriteLine("Cleaning Up");
            groupPrincipal.Dispose();
            userPrincipal.Dispose();
            systemContext.Dispose();

            Console.WriteLine();
            Console.WriteLine("Press Any Key to Continue");
            Console.ReadLine();
            return;
        }
    }
}

I feel this is kind of a Shoe or Glass bottle question, so I will give you a little lesson on using a hammer.

You mention that these machines are on a domain, it is much simpler to just do this with group policy.

Go in to group policy management (gpmc.msc) and create a new policy. Once you have a new policy created go to Computer Configuration->Prefrences->Local Users and Groups.

From there right click and go to New->Local User. In the new screen set the action to Create (you can click the help button to see the difference between the modes) and enter your info for the user in that screen.

One you click ok the user will show up on the screen on the local users and groups page. From there right click and go to New->Local Group. On the new page set the action to Update, use the drop-down to find the group name Administrators (built-in) and select it. In the bottom section click Add... and type in by hand the same name you put in from the previous screen (itadmin in your case). At the end it should look like this

the Local Users and Groups page will look like this

It is important to notice the Order column, the update on the administrator's group must have a higher order number than the user creation command.

One you have your group policy set up apply the policy to the machines that are in the lab (be it through OU targeting or Security Filtering, or WMI Filtering). On next reboot the local itadmin user will be created on each machine.

Also a interesting note, when you choose the user when selecting who to add to the local administrators group, you can click the ... and choose a user on the domain this will allow someone to use their domain login to be a local admin on a small set of computers without giving them rights to be a admin everywhere. However they will need to be able to log in using the domain for this to work, so if you are troubleshooting a network connectivity issue your current approach may be a better thing to do.